If you do choose .NET, starting by studying the official MS cert material will set you on the right path as well as prep you for the exams. Start with the MCTS Training Kit (Exam 70-515) Webmaster Community for Framework 4 and go from there.

Webmaster Community

 

Start with the MCTS Training Kit (Exam 70-515) Webmaster Community for Framework 4 and go from there.

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